Chemical Engineering presents: "Using the Transmission Line Impedance Model to Monitor Degradation Pathways in Fuel Cell Catalyst Layers" by E. Bradley Easton, Associate Professor, University of Ontario Institute of Technology.Typical catalyst layers (CL) employed in PEM fuel cells are composed of a carbon supported Pt catalyst bound together with an ionomer, most often Nafion. Both the carbon support and ionomer play a crucial role in optimizing the catalyst utilization by proving electronic and ionic conductive pathways, respectively, without hindering gas transport. Upon fuel cell operation, the catalyst layer can degrade by one of 3 primary pathways:
- 1. Loss of Pt surfaces area through Pt dissolution/Ostwald ripening
- 2. Corrosion of the carbon support
- 3.Degradation of the ionomer network
The contribution of each of these pathways depends upon CL compositions as well as the cell operating conditions. The extent of degradation is normally monitored in situ by cyclic voltammetry (CV) by measuring changes in the electrochemically active surface area (ECSA) of Pt. However, CV is limited in that it can only conclusively confirm the presence of the first pathway.
Contributions from the other 2 pathways are typically confirmed by post mortem analysis of the CL.
We have recently reported that the addition of periodic electrochemical impedance spectroscopy (EIS) measurements to an accelerated degradation testing protocol (ADTP) allows one to clearly diagnose the presence of the other 2 degradation pathways. By performing EIS under conditions where the transmission line model is valid, the presence of carbon corrosion can be clearly detected by a characteristic shift in the EIS response over time.
Likewise, the loss of ionic conductivity can also be observed through a unique change in the EIS response. Our methodology has since been extended and further validated by studying the stability of numerous commercial and in-house prepared catalysts using with different carbon supports. In this seminar, I will describe how EIS can be incorporated into almost any ADTP and how changes in the EIS response can be used for in situ diagnosis of degradation pathways that can be attributed to CL components.
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