@article{13, keywords = {2D Particle Synthesis for Photothermal Cancer Therapy}, author = {Farman Ullah and Darren Chung and Fan Ye and Reza Karimi and Joseph Sanderson and Kevin Musselman}, title = { [PDF] from wiley.com GetIt!@UWaterloo Femtosecond Laser Carburization of WS2 Flakes to W2C for Enhanced Photothermal Conversion Efficiency}, abstract = {
Photothermal therapy is a new, promising approach for treating cancer in a non‐invasive way. In this work, we synthesized a photothermally efficient nanomaterial, by exposing bulk WS2 powder, dispersed in carbon‐rich acetonitrile, to high‐intensity femtosecond laser pulses. The photothermal measurements showed a significantly higher rise in temperature and enhanced photothermal efficiency for the laser‐treated material. We attribute the enhancement to the formation of tungsten semi‐carbide (W2C), which we verified by morphological and structural characterization. The tungsten semi‐carbide was formed by laser‐induced carburization; intense laser pulses knock S atoms out of the WS2 lattice and dissociate the acetonitrile molecules, resulting in the formation of W2C. Interestingly, the hexagonal W2C had a two‐dimensional (2D) layered morphology like that of the WS2, suggesting its morphology is not
}, year = {2024}, journal = {Advanced Engineering Materials}, url = {https://onlinelibrary.wiley.com/doi/full/10.1002/adem.202302222}, doi = {10.1002/adem.202302222}, }