@article{16,
  keywords = {2D Particle Synthesis for Photothermal Cancer Therapy},
  author = {Fan Ye and Ahsan Ayub and Reza Karimi and Shawn Wettig and Joseph Sanderson and Kevin Musselman},
  title = {Defect‐Rich MoSe2 2H/1T Hybrid Nanoparticles Prepared from Femtosecond Laser Ablation in Liquid and Their Enhanced Photothermal Conversion Efficiencies},
  abstract = {<p>MoSe<sub>2</sub>&nbsp;2H/1T hybrid nanoparticles are prepared by femtosecond laser ablation of MoSe<sub>2</sub>&nbsp;powder in isopropyl alcohol with different laser powers and ablation times, and their formation mechanisms and photothermal conversion efficiencies (PTCEs) are studied. Two types of spherical nanoparticles are observed. The first type is onion-structured nanoparticles that are formed by nucleation on the surfaces of melted droplets followed by inward growth of {002} planes of MoSe<sub>2</sub>. The second type is polycrystalline nanoparticles, formed by coalescence of crystalline nanoclusters fragmented from the powder during the laser ablation. The nanoparticle size in all samples shows a bimodal distribution, corresponding to different fragmentation mechanisms. The 2H-to-1T phase transition in the nanoparticles is likely caused by electron doping from the laser-induced plasma. The PTCEs of the nanoparticles increase with laser power and ablation time; the highest PTCE is around 38%. After examining the bandgaps and the Urbach energies of the nanoparticles, it is found that the high PTCEs are primarily attributed to defects and structural disorder in the laser-synthesized nanoparticles, which allow absorption of photons with energies smaller than the bandgap energy and facilitate non-radiative recombination of photoexcited carriers.</p>
},
  year = {2023},
  journal = {Advanced Materials},
  volume = {35},
  chapter = {2301129},
  month = {2023/7},
  url = {https://onlinelibrary.wiley.com/doi/full/10.1002/adma.202301129},
  doi = {10.1002/adma.202301129},
}