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Harvard University (HU) is a private research university located in Cambridge, Massachusetts. The School of Engineering and Applied Science (SEAS) at HU aims to bring discovery and innovation to bear directly on improving human life and society in the 21st century [1]. As a part of this process, SEAS developed a Watermark Ink (W-INK) chip that identifies the surface tension of a liquid. The W-INK colourimetric indicator for organic liquids works based on the wettability of highly ordered Inverse Opal Films (IOF). The indicators mutually distinguish methanol, ethanol, and isopropanol, as shown in Figure 1. Applications of the W-INK system range from forgery detection to in-field liquid identification. To distinguish between highly similar liquids in the IOF (i.e., methanol, ethanol, and isopropanol), a quality control procedure must be developed to account for the variability between samples, ensuring reproducible liquid distinction results. Chemical tuning techniques for W-INK samples adjust the wettability of the IOF for use as a colourimetric indicator in a wide range of liquids. Resolution and distinction capabilities of each chemical tuning technique are suitable criteria for assessment.
Kevin Raymond, a co-op student from the University of Waterloo, was asked to investigate the W-INK quality control procedure and chemical tuning parameters that allow it to successfully identify a wide range of liquids and account for structural variability in samples.
The teaching objective of this case is to introduce W-INK, an indicator for organic liquids and analyze quality control and chemical tuning procedures that allow it to successfully identify liquids. The case can potentially be used in CHE 241 (Materials Science and Engineering), NE 125 (Introduction to Materials Science and Engineering), NE 100 (Introduction to Nanotechnology Engineering), and NE 226 (Characterization of Materials).
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Steve Lambert
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Email: steve@uwaterloo.ca
The University of Waterloo acknowledges that much of our work takes place on the traditional territory of the Neutral, Anishinaabeg and Haudenosaunee peoples. Our main campus is situated on the Haldimand Tract, the land granted to the Six Nations that includes six miles on each side of the Grand River. Our active work toward reconciliation takes place across our campuses through research, learning, teaching, and community building, and is co-ordinated within the Office of Indigenous Relations.