Holger Kleinke
Biography
Holger Kleinke's research focuses on finding and optimizing new thermoelectric materials. Thermoelectrics are capable of converting heat into electrical energy and vice versa. This environmentally friendly energy conversion currently has several applications, but is limited by its low efficiency. His research group is attempting to increase the efficiency so that thermoelectrics may be used to recover electricity from the nowadays abundant waste heat, e.g., in the exhaust of automobiles.
One of Holger Kleinke's newest projects is to utilize Cu ion mobility to lower the thermal conductivity of thermoelectric materials. This mobility has to be localized within each unit cell in order to inhibit Cu ion migration throughout the material, which would otherwise cause device degradation. Since the thermoelectric properties depend on the thermopower as well as on the electrical and thermal conductivity, various property measurements are routinely carried out in the group. The syntheses are guided by calculations performed by students who are fascinated by the theoretical aspects of chemical research.
One of Holger Kleinke's newest projects is to utilize Cu ion mobility to lower the thermal conductivity of thermoelectric materials. This mobility has to be localized within each unit cell in order to inhibit Cu ion migration throughout the material, which would otherwise cause device degradation. Since the thermoelectric properties depend on the thermopower as well as on the electrical and thermal conductivity, various property measurements are routinely carried out in the group. The syntheses are guided by calculations performed by students who are fascinated by the theoretical aspects of chemical research.
Research Interests
- Inorganic materials
- Solid-state chemistry
- Thermoelectric energy conversion
- Machine Learning
- Crystal structure predictions
- Quantum Materials
- Smart Materials
- Energy Materials
- Condensed Matter
- Next Generation Energy Systems
- Nanomaterials
- Renewable Energy
- Smart and Functional Materials
Education
- 1994, PhD, Chemistry, J.-G.-Universität Mainz, Germany
- 1991, MSc, Chemistry, W.-W.-Universität Münster, Germany
- 1988, BSc, Chemistry, W.-W.-Universität Münster, Germany
Awards
- 2002, Ontario Distinguished Researcher Award, Toronto, Canada
- 2001, Canada Research Chair in Solid State Chemistry (Tier II, NSERC), Ottawa, Canada
- 2000, Premier's Research Excellence Award (Province of Ontario), Toronto, Canada
- 1999, Fellowship for Habilitands (DFG), Bonn, Germany
- 1997-1999, Liebig-Fellowship (FCI, Fonds der Chemischen Industrie and BMBF, Bundesministerium für Bildung, und Forschung), Frankfurt, Germany
- 1995-1997, Postdoctoral Fellowship (DFG, Deutsche Forschungsgemeinschaft), Bonn, Germany
- 1994, PhD Award (FCI, Fonds der Chemischen Industrie), Frankfurt, Germany
Service
- 2023-present, Member, NSERC Evaluation Group for Chemistry
- 2022-present, Awards Committee
- 2015-present, Science Faculty Council
- 2013-present, Materials Nano Steering Committee
- 2021-2022, Chair, Health & Safety Committee
- 2021-2022, Promotions and Tenure Committee
- 2019-2020, Chair of the symposium Energy Conversion: Thermoelectrics and Solar Technologies Advancements in Thermoelectric Materials and Applications (with Drs. Lu and Zhao), The 20th IEEE International Conference on Nanotechnology, Montreal, Canada
- 2017-2020, Board of Directors, Waterloo Institute for Nanotechnology
- 2018-2019, Director, Nanotechnology Graduate Program
- 2016-2017, Interim Executive Director, Waterloo Institute for Nanotechnology
- 2016-2017, Chair of the Solid State Chemistry Symposium (with Dr. Thangadurai), 100th CSC Conference and Exhibition, Toronto, Canada
- 2015-2016, International Advisory Board Member, 35th International Conference on Thermoelectrics, Wuhan, China
Affiliations and Volunteer Work
- Member and Media Ambassador, Waterloo Institute for Nanotechnology
- 2016-2017, Interim Executive Director, Waterloo Institute for Nanotechnology
Teaching*
- CHEM 212 - Structure and Bonding
- Taught in 2020
- CHEM 400 - Special Topics in Chemistry
- Taught in 2019, 2021, 2022, 2024
- CHEM 713 - Chemistry of Inorganic Solid State Materials
- Taught in 2020, 2022, 2024
* Only courses taught in the past 5 years are displayed.
Selected/Recent Publications
- N. K. Barua, A. Golabek, A. O. Oliynyk, H. Kleinke, Experimentally Validated Machine Learning Predictions of Ultralow Thermal Conductivity for SnSe Materials, J. Mater. Chem. C 11, 11643-11652 (2023).
- L. T. Menezes, E. Gage, A. Assoud, M. Liang, P. S. Halasyamani, H. Kleinke, Sr6Ge3OSe11: A Rationally Designed Noncentrosymmetric Oxyselenide with Polar [GeOSe3] Building Blocks, Chem. Mater. 35, 3033-3040 (2023).
- C. Gayner, L. T. Menezes, Y. Natanzon, Y. Kauffmann, H. Kleinke, Y. Amouyal, Development of Nanostructured Bi2Te3 with High Thermoelectric Performance by Scalable Synthesis and Microstructure Manipulations, ACS Appl. Mater. Interf. 15, 13012-13024 (2023).
- Y.-C. Tseng, S. S. Razavi-Tousi, D. Ramirez, H. Kleinke, Advancing the Reliability of Thermoelectric Materials: a Case Study of Silicides through Statistics, Appl. Phys. Lett. 119, 193903/1-6 (2021).
- D. C. Ramirez, L. R. Macario, X. Cheng, M. Cino, D. Walsh, Y.-C. Tseng, H. Kleinke, Large Scale Solid State Synthetic Technique for High Performance Thermoelectric Materials: Magnesium-Silicide-Stannide, ACS Appl. Energy Mater. 3, 2130-2136 (2020).