ECE 639 - Fall 2013

ECE 639 - Characteristics and Applications of Non-Crystalline Silicon

Lectures will be 3 hours in length for a period of 12 weeks.

Instructor: Professor Andrei Sazonov
Office: E3 3142
Phone: 519-888-4567 x32863
Email: asazonov@uwaterloo.ca

Course Content
Date Topic Content
Week 1 Deposition and growth of a-Si:H and nc-Si
  • comparison of c-Si, poly-Si, nc-Si, and a-Si:H in terms of electronic properties, fabrication cost, deposition limitations and application areas
  • special features and inherent limits of each material
  • a-Si:H, poly-Si, nc-Si step-by-step review: growth, structure, states, doping, transport, applications
  • deposition techniques
  • growth process
  • thin film growth
  • process windows and process parameter control
Week 2 Structure of a-Si:H and nc-Si films
  • An introductory review: SRO, MRO, LRO
  • SRO: RDF, strained bonds, stress, defect formation
  • MRO: voids, stress, overcoordination
  • LRO: crystallinity, amorphous tissue
  • phonons, Raman, a-Si and nc-Si
  • hydrogen in silicon: bonding, FTIR, trapping and effusion, DSC
  • the role of hydrogen
Week 3 Electronic States and Defects in a-Si:H
  • extended and localized states, Anderson’s localization
  • a-Si:H bandgap structure, bandgap models
  • band tails, density of states measurements
  • Urbach energy, Tauc plot
  • defects in c-Si and in a-Si
  • defect charge states in a-Si:H, charge transfer
  • electron spin resonance
  • defect energy measurements
Week 4 Doping of a-Si:H
  • doping mechanisms in c-Si, nc-Si, and a-Si:H; doping efficiency
  • relationship between the doping and defects
  • doping models
Week 5 Metastability in a-Si:H
  • stable and metastable states, equilibration
  • relationship between the structure and metastability: models and experiments
  • metastability and electronic properties
  • metastable effects in a-Si:H (Staebler-Wronski effect, threshold voltage shift, particle bombardment, doping efficiency change)
Week 6 Electronic Transport in a-Si:H and nc-Si
  • types of conductivity in c-Si, μc-Si, and a-Si:H; transport through extended, localized, and defect states
  • temperature dependence, Meyer-Neldel rule
  • carrier mobility
Week 7 Interfaces and Contacts with a-Si:H and nc-Si
  • Schottky contacts, ohmic contacts
  • interface defects, their measurements
  • relationship between the structure, material quality, and the interface states
  • interfaces with doped layers, nitrides, and oxides
Week 8 Poly-Si and nc-Si
  • fabrication
  • structure
  • carrier transport
  • impurities and doping
  • device applications
Week 9 Device Applications: photovolatics
  • physical principles
  • energy conversion losses
  • device structure
  • performance characterization
  • different materials for solar cells (poly-Si, mc-Si, nc-Si, a-Si:H, quantum structures)
Week 10 Device Applications: displays and imaging
  • different types of displays
  • liquid crystal displays: physical basics
  • passive matrix and active matrix displays
  • physical basics of imaging
  • visible, IR, UV, and x-ray imaging
  • device structures and fabrication
Week 11 Device Applications: macroelectronics
  • the concept of macroelectronics
  • consumer electronics and disposable electronics
  • flexible electronics
  • "sensitive skin" and "smart clothes"
  • biomedical sensors and systems
Week 12 Course Project Presentations  

Textbook: There is no "official" textbook.

Recommended literature:

  1. R.A. Street, Hydrogenated Amorphous Silicon, Cambridge University Press, 1990.
  2. R.A. Street (ed.) Technology and Applications of Amorphous Silicon, Springer, 2000.