The Waterloo Institute for Nanotechnology (WIN) presents a Distinguished Lecture by Professor Lynden A. Archer, William C. Hooey Director and James A. Friend Family Distinguished Professor of Chemical and Biomolecular Engineering at Cornell University, United States.
Lecture: 3:00-4:00pm
Reception: 4:00-5:00pm
Electrolyte Design Principles for Lithium Metal Batteries
Abstract
This talk considers the stability of electrodeposition of reactive metals such as lithium and sodium on planar electrodes with the goal of enabling next-generation secondary batteries based on lithium and sodium metal anodes. Such batteries promise substantial improvements in electrochemical energy storage over todays’s state-of-the art lithium ion technology and are under active investigation worldwide.
Development of a practical rechargeable lithium metal battery (LMB) remains a challenge due to uneven lithium electrodeposition and formation of ramified denderitic electrodeposits during repeated cycles of charge and discharge. Known consequences of unstable electrodeposition in LMBs include accumulation of electrically disconnected regions of the anode or “dead lithium”, thermal runaway of the cell, and internal short circuits, which limit cell lifetime and may pose serious hazards if a flammable, liquid electrolyte is used in a LMB. Lithium-ion batteries (LIBs) are designed to eliminate the most serious of these problems by hosting the lithium in a graphitic carbon substrate, but this configuration is not entirely immune from uneven lithium plating and dendrite formation. Specifically, the small potential difference separating lithium intercalation into versus lithium plating onto graphite, means that a too quickly charged or overcharged LIB may fail by similar mechanisms as a LMB.
Using a continuum transport analysis for electrodeposition in a structured electrolyte in which a fraction of the anions are fixed in space, the talk will show that electrodeposition at the lithium anode can be stabilized through rational design of the electrolyte and salt. Building upon these ideas, the talk will explore structure and transport in novel nanoporous hybrid electrolyte configurations designed to stabilize metal anodes against dendritic electrodeposition and premature failure. Finally, the talk will explore an application of these electrolyte designs for LMBs to evaluate stability conditions deduced from theory.
Professor Lynden Archer
Lynden
Archer
is
the
William
C.
Hooey
Director
and
James
A
Friend
Family
Distinguished
Professor
of
Chemical
and
Biomolecular
Engineering
at
Cornell
University.
His
research
focuses
on
transport
properties
of
polymers
and
polymer/particle
hybrids,
and
their
applications
for
electrochemical
energy
storage
technology.
Archer
received
his
Ph.D.
in
chemical
engineering
from
Stanford
University
in
1993
and
the
bachelor
of
science
degree
in
chemical
engineering
(polymer
science)
from
the
University
of
Southern
California
in
1989.
He
is
a
fellow
of
the
American
Physical
Society.
His
research
contributions
have
been
recognized
with
various
awards,
including
the
AICHE
Nanoscale
Science
and
Engineering
Forum
award,
the
National
Science
Foundation
Award
for
Special
Creativity,
the
NSF
Distinguished
Lectureship,
and
the
American
Institute
of
Chemical
Engineer’s
MAC
Centeniell
Engineer
award.
At
Cornell,
he
has
been
recognized
with
the
James
&
Mary
Tien
Excellence
in
Teaching
Award
and
twice
with
the
Merrill
Presidential
award
as
the
most
influential
member
of
the
Cornell
faculty
selected
by
a
Merrill
Presidential
Scholar
awardee.